The only thing that has turned me off is the fact that I'm spoiled by the latest versions of .Net and C#, which I now take for granted. Having to go back to Unity's version of these kind of makes me cringe, so I'd say getting those up to date would be removing the biggest obstacle to me giving Unity a go.
What are you missing? Honestly past linq nothing has changed that much and you get that in unity
So your very valid question forced me to challenge my own preconceptions about Unity and I discovered that C# in Unity is more up to date than I thought. That then led me to wonder why I still have an aversion to it and the thoughts that come to mind are that I read an article somewhere stating it doesn't really play well with version control (outside of Unity's own proprietary add-on solution?) which bugs me a lot, as that's something I like control over. I'm also very picky about visuals and only the as-yet-unreleased version 5 has shown lighting that lives up to my own unreasonable standards. And then there's the fact that I like to reinvent the wheel. Guilty as charged.
For version control now that MS bought off the visual studio plugin it's free to use iirc, so i guess for code you could just work with visual studio projects and use TFS. Also for visuals it really depend if you could "just unity" (but if so it's a waste as your missing it's greatest strenght) or unity + asset store offerings (which are cheap compared to unity itself). You can find plenty of eye candy there, last i toyed with unity there were even realtime GI implémentations on the way to the store (not sure how that went). Here are a few products i like that produce muchos eye candy for unity
http://tcparticles.tinycubestudio.com/ (gpgpu massive amount of particules)
http://www.noesisengine.com/noesis_gui_features.htm (basically WPF subset usable as your GUI Framework)
http://www.marmoset.co/skyshop (IBL for unity)
And plenty more of course, but the asset store was always what sold me in unity, makes the engine go from "meh, nice user friendly but not impressive" to "wow" for a few more $$$ compared to the base license price.