Hey there 48K ;) (EDIT: And welcome to gamedev, it's a great site for getting your maths/programming questions answered in a friendly way. You may want to change your email preferences though so you don't get spammed with "X posted a thread about..." emails).
I'm sure MATLAB will allow you to do statistical simulations via programming but haven't got any experience of using it.
On WoS I recommended Python, that's a LOT easier than line-number era BASIC and has some really nice features for doing maths/stats stuff (like built in vectors, lists, dictionaries, support for bignums [arbitrarily large numbers], etc.).
Java is another option but that is going to be more daunting to start off with if you're not used to compile/link style programs and is frankly a beast.
Python homepage:
EDIT: You should probably go into more detail about what you are trying to achieve as well, something to do with simulating splitting DNA or RNA strands I believe?