Well since everyone already did a good job of covering the advantages from a technical and programming viewpoint I"d add what the advantage is for most end-users:
"Even systems with as little as 2GB can be prevented from having all their memory usable under 32-bit Windows because of chipsets that aggressively reserve memory regions for devices. Our shared family computer, which we purchased only a few months ago from a major OEM, reports that
only 1.97GB of the 2GB installed is available:
"
I've seen cases where people with high-end SLI videocards that eat up a 1GB of ram running on 32-bit versions of Windows ending up with as little as 1.5GB of ram they could use on their PC even though they had 4GB or more installed!
So I'd say that happens to you your going to want 64-bit Windows to reclaim that lost memory.
[size="2"]Don't talk about writing games, don't write design docs, don't spend your time on web boards. Sit in your house write 20 games when you complete them you will either want to do it the rest of your life or not * Andre Lamothe